Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part II

被引:13
作者
Alho, MAM [1 ]
D'Accorso, NB [1 ]
机构
[1] Univ Buenos Aires, Fac Ciencias Exactas & Nat, Dept Quim Organ, CIHI Car, RA-1428 Buenos Aires, DF, Argentina
关键词
D O I
10.1002/jhet.5570370423
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The syntheses of 2,3-dihydro-1,3,4-thiadiazoles and 1,3,4-thiadiazoles from 1,2-O-isopropylidene-alpha-D-xylo-1,5-pentadialdo-1,4-furanose thiosemicarbazone are described. The new compounds as well as the intermediate products are physically and spectroscopically characterized. We discuss a possible mechanistic pathway for heterocyclization in this particular substrate, using computational calculation.
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页码:811 / 814
页数:4
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