Melt processable copolyimides based on 4,4′-bis(3-aminophenoxy)biphenyl

被引:25
作者
Tamai, S
Oikawa, H
Ohta, M
Yamaguchi, A
机构
[1] Mitsui Toatsu Chem Inc, Omuta Lab, Omuta City, Japan
[2] Mitsui Toatsu Chem Inc, Cent Res Inst, Sakae Ku, Yokohama, Kanagawa, Japan
关键词
copolyimide; 4,4 '-bis(3-aminophenoxy)biphenyl; melt processable;
D O I
10.1016/S0032-3861(97)00491-6
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Copolyimides based on 4,4'-bis(3-aminophenoxy)biphenyl (abbreviated to BAB) and pyromellitic dianhydride (PMDA) were synthesised with 4,4'-oxydianiline (4,4'-ODA) and/or 3,3',4,4'-biphenyl tetracarboxylic dianhydride (BPDA). Basic property and melt processability of synthesised copolyimides were investigated. Crystallisation property of these copolyimides were dependent on contents of 4,4'-ODA and/or BPDA. Melt processability of copolyimides obtained from BAB, 4,4'-ODA and PMDA were dependent on contents of 4,4'-ODA. Melt viscosities and Tg's of copolyimides obtained from BAB, PMDA and BPDA were decreased according to increase of BPDA contents. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1945 / 1949
页数:5
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