Enhanced Li-Transport on the Nanoscale: TiO2-B Nanowires

被引：7

作者：

Koudriachova, M. V. ^{[1
]}

机构：

[1] UCL, London WC1E 6BT, England

来源：

JOURNAL OF NANO RESEARCH | 2010年 / 11卷

关键词：

TiO2-B; nanowires; electrode materials; Li-batteries; diffusion; ab initio simulations; LITHIUM INTERCALATION; INSERTION;

D O I：

10.4028/www.scientific.net/JNanoR.11.159

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The origin of enhanced intercalation of Li-ions into TiO2-B is being examined using first principles density functional calculations. Using advanced simulation techniques, we built a comprehensive description of Li-intercalation into TiO2-B and demonstrate that it acts as a capacitor at [Li]/[Ti] <= 0.5, while at higher concentrations the insertion capacity is limited by Li self-diffusion.

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收藏

页码：159 / 164

页数：6

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