Reversible and irreversible conformational changes in poly(isocyanide)s: a remote stereoelectronic effect

被引：10

作者：

Amabilino, DB

Serrano, JL

Veciana, J

机构：

[1] CSIC, Inst Ciencia Mat Barcelona, Bellaterra 08193, Catalonia, Spain

[2] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 03期

关键词：

D O I：

10.1039/b411449c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Poly( isocyanide)s prepared by diastereoselective polymerisation of two chiral monomers, which differ only in the presence of a nitro-group adjacent to the stereogenic group, exhibit long range chiral induction, but a surprising influence of a remote substituent on the conformation and stability of the secondary structure in the macromolecules.

引用

收藏

页码：322 / 324

页数：3

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