The great escape from antiaromaticity: Reduction of strained pyrenes

被引：19

作者：

Aprahamian, I

Bodwell, GJ

Fleming, JJ

Manning, GP

Mannion, MR

Sheradsky, T

Vermeij, RJ

Rabinovitz, M ^{[1
]}

机构：

[1] Hebrew Univ Jerusalem, Dept Organ Chem, IL-91904 Jerusalem, Israel

[2] Mem Univ Newfoundland, Dept Chem, St Johns, NF A1B 3X7, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 07期

关键词：

D O I：

10.1021/ja0291991

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The two-electron reduction of strained pyrenes ([7](2,7)pyrenophanes) with lithium metal leads to the formation of a new σ-bond as a means to escape" strained antiaromaticity. Copyright © 2003 American Chemical Society."

引用

页码：1720 / 1721

页数：2

共 24 条

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