Ab-initio construction of some crystalline 3D Euclidean networks

被引:18
作者
Hyde, ST [1 ]
Ramsden, S [1 ]
Di Matteo, T [1 ]
Longdell, JJ [1 ]
机构
[1] Australian Natl Univ, Res Sch Phys Sci, Dept Appl Math, Canberra, ACT 0200, Australia
关键词
hyperbolic geometry; crystalline graphs; chemical frameworks;
D O I
10.1016/S1293-2558(02)00079-1
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
We describe a technique for construction of 3D Euclidean (E-3) networks with partially-prescribed rings. The algorithm starts with 2D hyperbolic (H-2) tilings, whose symmetries are commensurate with the intrinsic 2D symmetries of triply periodic minimal surfaces (or infinite periodic minimal surfaces, IPMS). The 2D hyperbolic pattern is then projected from H-2 to E-3, forming 3D nets. Examples of cubic and tetragonal 3-connected nets with up to 288 vertices per unit cell, each linking a pair of 6-rings and a single 8-ring, are derived by projection onto the P, D, Gyroid and I-WP IPMS. A single example of a projection from close-packed trees in H-2 to E-3 (via the D surface) is also shown, that leads to a quartet of interwoven equivalent chiral nets. The configuration describes the channel system of a novel quadracontinuous branched minimal surface that is a chiral foam with four identical, open bubbles. (C) 2003 Editions scientifiques et medicales Elsevier SAS. All rights reserved.
引用
收藏
页码:35 / 45
页数:11
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