Chemical versus solvent extraction treatment: Comparison and influence on polyester based bio-composite mechanical properties

被引:15
作者
Krouit, Mohammed [1 ]
Belgacem, Mohamed Naceur [1 ]
Bras, Julien [1 ]
机构
[1] Grenoble INP Pagora, CNRS, Lab Genie Procedes Papetiers, UMR 5518, F-38402 St Martin Dheres, France
关键词
Natural Fibre composite; Polymer Matrix composites (PMCs); Surface properties; Thermomechanical; CELLULOSE FIBERS; SURFACE; POLYMERIZATION; POLYETHYLENE;
D O I
10.1016/j.compositesa.2010.01.014
中图分类号
T [工业技术];
学科分类号
120111 [工业工程];
摘要
The influence of chemical and solvent extraction compatibilising techniques on the mechanical properties of poly-lactic acid (PLA) and MaterBi(R)-polyester (PEM) based bio-composites are compared. First, fibres were chemically grafted with two fatty chains: stearic anhydride and octadecylisocyanate. Grafted fibres were characterised by FTIR and elemental analyses. Contact angle measurements show the hydrophobisation of the fibres in spite of very low surface grafting. Extracted and non-grafted fibres were prepared to be used as references. PEM and PLA-based composites with 30% w/w were prepared by compression moulding. Their mechanical properties were studied. It was found that chemical and solvent treatment of the fibres improved the reinforcement effect in the case of a PEM matrix and the Young modulus increased by 96%. An important conclusion is that solvent extraction is as efficient as chemical grafting for compatibilisation treatment. These results open new perspectives to prepare industrially efficient bio-composite. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:703 / 708
页数:6
相关论文
共 21 条
[1]
Short natural-fibre reinforced polyethylene and natural rubber composites: Effect of silane coupling agents and fibres loading [J].
Abdelmouleh, M. ;
Boufi, S. ;
Belgacem, M. N. ;
Dufresne, A. .
COMPOSITES SCIENCE AND TECHNOLOGY, 2007, 67 (7-8) :1627-1639
[2]
Bastioli C., 2005, Handbook of biodegradable polymers
[3]
Surface characterization of cellulose fibres by XPS and inverse gas chromatography [J].
Belgacem, MN ;
Czeremuszkin, G ;
Sapieha, S ;
Gandini, A .
CELLULOSE, 1995, 2 (03) :145-157
[4]
The surface modification of cellulose fibres for use as reinforcing elements in composite materials [J].
Belgacem, MN ;
Gandini, A .
COMPOSITE INTERFACES, 2005, 12 (1-2) :41-75
[5]
BELGACEM MN, 2008, MONOMERS POLYM COMPO, P562
[6]
Chemical modification of the surface of cellulosic fibres. 2. Introduction of alkenyl moieties via condensation reactions involving isocyanate functions [J].
Botaro, VR ;
Gandini, A .
CELLULOSE, 1998, 5 (02) :65-78
[7]
A small angle X-ray scattering study of pore structure in Tencel® cellulose fibres and the effects of physical treatments [J].
Crawshaw, J ;
Cameron, RE .
POLYMER, 2000, 41 (12) :4691-4698
[8]
Composites based on acylated cellulose fibers and low-density polyethylene: Effect of the fiber content, degree of substitution and fatty acid chain length on final properties [J].
Freire, Carmen S. R. ;
Silvestre, Armando J. D. ;
Neto, Carlos Pascoal ;
Gandini, Alessandro ;
Martin, Loli ;
Mondragon, Inaki .
COMPOSITES SCIENCE AND TECHNOLOGY, 2008, 68 (15-16) :3358-3364
[9]
Direct organocatalytic polymerization from cellulose fibers [J].
Hafrén, J ;
Córdova, A .
MACROMOLECULAR RAPID COMMUNICATIONS, 2005, 26 (02) :82-86
[10]
Immobilization of glucoamylase on polypropylene fibers modified by radiation induced graft copolymerization [J].
Kamal, H. ;
Sabry, Gilane M. ;
Lotfy, Salah ;
Abdallah, Nadia M. ;
Rosiak, J. ;
Hegazy, El-Sayed A. .
JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2008, 45 (01) :65-75