Desymmetrization of meso-dialdehydes with optically active cyclopentadienyldialkoxyallyltitanium complexes

被引：19

作者：

BouzBouz, S ^{[1
]}

Popkin, ME ^{[1
]}

Cossy, J ^{[1
]}

机构：

[1] Ecole Super Phys & Chim Ind, Chim Organ Lab, CNRS, F-75231 Paris 05, France

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 22期

关键词：

D O I：

10.1021/ol0057434

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Optically active cyclopentadienyldialkoxyallyltitanium complexes have been employed for the desymmetrization of meso-dialdehydes. Allylation of these dialdehydes and subsequent oxidation afford chiral lactones with good diastereoselectivity and excellent enantioselectivity.

引用

页码：3449 / 3451

页数：3

共 15 条

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