Preparation of carbon nanotube encapsulated copper nanowires and their use as a reinforcement for Y-Ba-Cu-O superconductors

被引:30
作者
Hwang, GL
Hwang, KC [1 ]
Shieh, YT
Lin, SJ
机构
[1] Natl Yunlin Univ Sci & Technol, Dept Chem Engn, Yunlin 640, Taiwan
[2] Natl Tsing Hua Univ, Dept Chem, Hsinchu 300, Taiwan
[3] Natl Tsing Hua Univ, Dept Mat Engn, Hsinchu 300, Taiwan
关键词
D O I
10.1021/cm020747j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Copper nanowires with multiwall carbon nanotubes (MWNTs) encapsulated inside were prepared via surface modification of MWNTs followed by chemical deposition of copper on surfaces. These MWNTs-encapsulated copper nanowires were investigated as a reinforcement to improve the mechanical strength of the Y-Ba-Cu-O superconductor. TEM and SEM reveal that MWNTs are uniformly coated by copper and the diameters of the prepared MWNTs-encapsulated Cu nanowires range from 50 to 150 nm and the lengths are up to several micrometers. These MWNTs-containing Cu nanowires could effectively improve the hardness of the Y-Ba-Cu-O without sacrificing its superconductivity. The Vicker's hardness of the Y-Ba-Cu-O is reinforced by similar to20% after 5 wt % of MWNTs incorporation. This study presents the first result that demonstrates the feasibility of the reinforcement of brittle YBaCuO superconductor by using MWNTs.
引用
收藏
页码:1353 / 1357
页数:5
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