New aggregation-induced emission enhancement materials combined triarylamine and dicarbazolyl triphenylethylene moieties

被引:90
作者
Li, Haiyin
Chi, Zhenguo [1 ]
Xu, Bingjia
Zhang, Xiqi
Yang, Zhiyong
Li, Xiaofang
Liu, Siwei
Zhang, Yi
Xu, Jiarui
机构
[1] Sun Yat Sen Univ, PCFM Lab, Guangzhou 510275, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
INTRAMOLECULAR CHARGE-TRANSFER; QUINOL-TYPE FLUOROPHORES; DERIVATIVES; MOLECULES; BEHAVIOR;
D O I
10.1039/c0jm00599a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new class of compounds containing triarylamine and dicarbazolyl triphenylethylene moieties with high thermal stability and aggregation-induced emission enhancement properties was synthesized. The glass transition temperature and 5% weight loss temperature of 3B-TPA are up to 214.3 degrees C and 516.8 degrees C, respectively. The compounds exhibited significant photoinduced intramolecular charge-transfer properties. The aggregation considerably affected the pi-pi* transition and resulted in 6-7 nm red shift of the pi-pi* absorption wavelength at the peak in UV-vis spectra. The compounds could emit intense blue-green light in aggregated states.
引用
收藏
页码:6103 / 6110
页数:8
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