Synthesis, crystal structure, and magnetic properties of a one-dimensional polymeric copper(II) complex containing an unusual 1,1′-bicoordinated oxalato bridge

被引:83
作者
Castillo, O
Luque, A
Sertucha, J
Román, P
Lloret, F
机构
[1] Univ Basque Country, Dept Quim Inorgan, E-48080 Bilbao, Spain
[2] Univ Valencia, Fac Quim, Dept Quim Inorgan, E-46100 Valencia, Spain
关键词
D O I
10.1021/ic000543+
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The crystal structure and the magnetic properties of the compound [Cu(mu -oxalato-O,O')(H2O)(4-aminopyridine)(2)](n), the first transition metal extended structure that exhibits a bridging oxalate anion. n a 1,1'-cis-bidentate coordination mode, are reported.
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页码:6142 / +
页数:4
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