Novel fluorine containing polyfluorenes with efficient blue electroluminescence

被引:58
作者
Assaka, AM
Rodrigues, PC
de Oliveira, ARM
Ding, LM
Bin, H
Karasz, FE
Akcelrud, L
机构
[1] Univ Fed Parana, Ctr Politecn, Dept Quim, BR-81531990 Curitiba, Parana, Brazil
[2] Univ Fed Parana, Ctr Politecn, Inst Technol Desenvolvimento LACTEC, BR-81531990 Curitiba, Parana, Brazil
[3] Univ Massachusetts, Dept Polymer Sci & Engn, Amherst, MA 01003 USA
[4] Univ Tennessee, Dept Mat Sci & Engn, Knoxville, TN 37996 USA
关键词
polyfluorenes; electroluminescence; fluorinated polyfluorenes;
D O I
10.1016/j.polymer.2004.07.072
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The synthesis, structural characterization, photo and electroluminescence, thermal and electrochemical properties of a new fluorinated fluorene-containing copolymer are described. The copolymer is formed by alternating mers of [2,3,5,6 tetrafluoro-1,4 phenylene] and [9,9'dihexyl-2,7 fluorene] and emits blue light with low turn on voltages. The EL performance of the fluorinated copolymer was superior to those of the non-fluorinated analog copolymer and of the corresponding poly(9,9'dihexyl-2,7 polyfluorene) homopolymer. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:7071 / 7081
页数:11
相关论文
共 47 条
[1]   Interchain luminescence in poly(acetoxy-p-phenylene vinylene) [J].
Aguiar, M ;
Fugihara, MC ;
Hümmelgen, IA ;
Péres, LO ;
Garcia, JR ;
Gruber, J ;
Akcelrud, L .
JOURNAL OF LUMINESCENCE, 2002, 96 (2-4) :219-225
[2]  
Aguiar M, 1998, MACROMOL CHEM PHYSIC, V199, P1255, DOI 10.1002/(SICI)1521-3935(19980701)199:7<1255::AID-MACP1255>3.0.CO
[3]  
2-7
[4]   Electroluminescent polymers [J].
Akcelrud, L .
PROGRESS IN POLYMER SCIENCE, 2003, 28 (06) :875-962
[5]   Electrical and photoinduced degradation of polyfluorene based films and light-emitting devices [J].
Bliznyuk, VN ;
Carter, SA ;
Scott, JC ;
Klärner, G ;
Miller, RD ;
Miller, DC .
MACROMOLECULES, 1999, 32 (02) :361-369
[6]   Polymer light emission: control of properties through chemical structure and morphology [J].
Bradley, DDC ;
Grell, M ;
Grice, A ;
Tajbakhsh, AR ;
O'Brien, DF ;
Bleyer, A .
OPTICAL MATERIALS, 1998, 9 (1-4) :1-11
[7]   Synthesis, chain rigidity, and luminescent properties of poly[(1,3-phenyleneethynylene)-alt-tris(2,5-dialkoxy-1,4-phenyleneethynylene)]s [J].
Chu, QH ;
Pang, Y ;
Ding, LM ;
Karasz, FE .
MACROMOLECULES, 2002, 35 (20) :7569-7574
[8]   Characterization of the interface dipole at organic/metal interfaces [J].
Crispin, X ;
Geskin, V ;
Crispin, A ;
Cornil, J ;
Lazzaroni, R ;
Salaneck, WR ;
Brédas, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (27) :8131-8141
[9]   Synthesis and characterization of alternating copolymers of fluorene and oxadiazole [J].
Ding, JF ;
Day, M ;
Robertson, G ;
Roovers, J .
MACROMOLECULES, 2002, 35 (09) :3474-3483
[10]   FUSIBLE CONDUCTING POLY(9-ALKYLFLUORENE) AND POLY(9,9-DIALKYLFLUORENE) AND THEIR CHARACTERISTICS [J].
FUKUDA, M ;
SAWADA, K ;
YOSHINO, K .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1989, 28 (08) :L1433-L1435