Single-step conversion of N-benzyl, N-trityl and N-diphenylmethyl amines to t-butyl carbamates using polymethylhydrosiloxane

被引:25
作者
Chandrasekhar, S [1 ]
Babu, BN [1 ]
Reddy, CR [1 ]
机构
[1] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India
关键词
polymethylhydrosiloxane; di-tert-butyl dicarbonate;
D O I
10.1016/S0040-4039(03)00172-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
t-Butyl carbamates were obtained efficiently in high yields from the corresponding N-benzyl, N-trityl and N-diphenylmethyl precursors in a single-step reductive transformation employing polymethylhydrosiloxane and di-t-butyl dicarbonate under Pd(OH)(2)/C catalysis. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2057 / 2059
页数:3
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