Enhanced electrochemiluminescence of luminol-O2 system at gold-hydrophobic ionic liquid|water interface

被引：22

作者：

Rong, Jiefeng

Chi, Yuwu ^{[1
]}

Zhang, Yuanjin

Chen, Lichan

Chen, Guonan

机构：

[1] Fuzhou Univ, Coll Chem & Chem Engn, MOE, Key Lab Anal & Detect Technol Food Safety, Fuzhou 350108, Fujian, Peoples R China

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2010年 / 12卷 / 02期

关键词：

Ionic liquid; Luminol; Electrochemiluminescence; Electrochemistry; ELECTROGENERATED CHEMILUMINESCENCE; HORSERADISH-PEROXIDASE; ASCORBIC-ACID; ELECTRODE; DOPAMINE; OXIDE; CELL;

D O I：

10.1016/j.elecom.2009.12.012

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A hydrophobic thiol-functionalized ionic liquid (IL) was synthesized and immobilized tightly on a gold electrode surface via Au-S bond to construct a stable Au-IL vertical bar water interface. At the Au-IL vertical bar water interface, the electrochemiluminescence (ECL) of luminol-O-2 system was investigated. The ECL intensity of luminol-O-2 system at the Au-IL vertical bar water interface was much larger and more stable than that at Au vertical bar water interface. The enhanced ECL mechanism at the Au-IL vertical bar water interface was studied and discussed in details. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：270 / 273

页数：4

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