Umpolung of a metal-carbon bond: A potential route to porphyrin-based methane functionalization catalysts

被引：57

作者：

Nelson, AP ^{[1
]}

DiMagno, SG ^{[1
]}

机构：

[1] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2000年 / 122卷 / 35期

关键词：

D O I：

10.1021/ja001380r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：8569 / 8570

页数：2

共 22 条

[1] SELECTIVE INTERMOLECULAR CARBON-HYDROGEN BOND ACTIVATION BY SYNTHETIC METAL-COMPLEXES IN HOMOGENEOUS SOLUTION [J].

ARNDTSEN, BA ;

BERGMAN, RG ;

MOBLEY, TA ;

PETERSON, TH .

ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (03) :154-162

[2] ACTIVATION OF ALKANES WITH ORGANOTRANSITION METAL-COMPLEXES [J].

BERGMAN, RG .

SCIENCE, 1984, 223 (4639) :902-908

[3] EQUILIBRIUM ACIDITIES IN DIMETHYL-SULFOXIDE SOLUTION [J].

BORDWELL, FG .

ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (12) :456-463

[4] Thermal, catalytic, regiospecific functionalization of alkanes [J].

Chen, HY ;

Schlecht, S ;

Semple, TC ;

Hartwig, JF .

SCIENCE, 2000, 287 (5460) :1995-1997

[5]

Collman J.P., 1987, PRINCIPLES APPL ORGA

[6]

HILL CJ, 1989, ACTIVIATION FUNCTION

[7] 2,3,7,8,12,13,17,18-octafluoro-5,10,15,20-tetraphenylporphyrin: First synthesis and X-ray crystal structure of the Zn-II complex [J].

Leroy, J ;

Bondon, A ;

Toupet, L ;

Rolando, C .

CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (11) :1890-1893

[8] FORMATION AND REACTIVITY OF (OCTAETHYLTETRAAZAPORPHYRINATO)RHODIUM COMPLEXES [J].

NI, YP ;

FITZGERALD, JP ;

CARROLL, P ;

WAYLAND, BB .

INORGANIC CHEMISTRY, 1994, 33 (09) :2029-2035

[9]

Pauling L., 1960, NATURE CHEM BOND

[10] THE TRANSITION-METAL HYDROGEN-BOND [J].

PEARSON, RG .

CHEMICAL REVIEWS, 1985, 85 (01) :41-49

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