Microwave-enhanced ruthenium-catalysed atom transfer radical additions

被引:42
作者
Borguet, Yannick [1 ]
Richel, Aurore [1 ]
Delfosse, Sbastien [1 ]
Leclerc, Alain [1 ]
Delaude, Lionel [1 ]
Demonceau, Albert [1 ]
机构
[1] Univ Liege, Macromol Chem & Organ Catalysis Lab, B-4000 Liege, Belgium
关键词
catalysis; microwave; olefins; radicals and radical reactions; ruthenium and compounds;
D O I
10.1016/j.tetlet.2007.07.029
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The first monomode microwave-assisted atom transfer radical additions (ATRA) of carbon tetrachloride to various olefins were successfully performed, affording the adducts with almost quantitative yields in less than 10 min at 160 'C. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:6334 / 6338
页数:5
相关论文
共 61 条
  • [1] MICROWAVE-ASSISTED CATALYTIC ADDITION OF HALOCOMPOUNDS TO ALKENES
    ADAMEK, F
    HAJEK, M
    [J]. TETRAHEDRON LETTERS, 1992, 33 (15) : 2039 - 2042
  • [2] Microwave-assisted synthesis of N-heterocyclic carbene precursors
    Aidouni, A
    Demonceau, A
    Delaude, L
    [J]. SYNLETT, 2006, (03) : 493 - 495
  • [3] MICROWAVE-INDUCED ORGANIC-REACTION ENHANCEMENT CHEMISTRY .2. SIMPLIFIED TECHNIQUES
    BOSE, AK
    MANHAS, MS
    GHOSH, M
    SHAH, M
    RAJU, VS
    BARI, SS
    NEWAZ, SN
    BANIK, BK
    CHAUDHARY, AG
    BARAKAT, KJ
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (25) : 6968 - 6970
  • [4] Ultra-fast microwave enhanced reversible addition-fragmentation chain transfer (RAFT) polymerization: monomers to polymers in minutes
    Brown, Steven L.
    Rayner, Christopher M.
    Graham, Susan
    Cooper, Andrew
    Rannard, Steven
    Perrier, Sebastien
    [J]. CHEMICAL COMMUNICATIONS, 2007, (21) : 2145 - 2147
  • [5] Synthesis and application of new N-heterocyclic carbene ruthenium complexes in catalysis:: A case study
    Delaude, L
    Demonceau, A
    Noels, AF
    [J]. CURRENT ORGANIC CHEMISTRY, 2006, 10 (02) : 203 - 215
  • [6] Delaude L, 2004, TOP ORGANOMETAL CHEM, V11, P155
  • [7] Tuning of ruthenium N-heterocyclic carbene catalysts for ATRP
    Delaude, L
    Delfosse, S
    Richel, A
    Demonceau, A
    Noels, AF
    [J]. CHEMICAL COMMUNICATIONS, 2003, (13) : 1526 - 1527
  • [8] Single-mode microwave-assisted atom transfer radical polymerization catalyzed by [RuCl2(p-cymene)(PCy3)]
    Delfosse, Sebastien
    Borguet, Yannick
    Delaude, Lionel
    Demonceau, Albert
    [J]. MACROMOLECULAR RAPID COMMUNICATIONS, 2007, 28 (04) : 492 - 503
  • [9] DEMONCEAU A, 2005, POLYM PREPR, V46, P295
  • [10] THE USE OF MICROWAVE-OVENS FOR RAPID ORGANIC-SYNTHESIS
    GEDYE, R
    SMITH, F
    WESTAWAY, K
    ALI, H
    BALDISERA, L
    LABERGE, L
    ROUSELL, J
    [J]. TETRAHEDRON LETTERS, 1986, 27 (03) : 279 - 282