Dipeptides as microporous materials

被引：136

作者：

Soldatov, DV ^{[1
]}

Moudrakovski, IL ^{[1
]}

Ripmeester, JA ^{[1
]}

机构：

[1] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 46期

关键词：

chirality; inclusion compounds; microporosity; peptides; zeolites;

D O I：

10.1002/anie.200460952

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Robust porous frameworks are formed by the dipeptides L-Ala-L-Val (see structure) and L-Val-L-Ala that have a high capacity and selectivity for gas sorption. The dipeptides assemble through hydrogen bonds as a S1 helix to form channels with average diameters of 5.13 and 4.90 Å, respectively. (Figure presented).

引用

页码：6308 / 6311

页数：4

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