Meso aryl heptaphrins:: The first 30π aromatic expanded porphyrins with an inverted structure

被引:37
作者
Anand, VRG
Pushpan, SK
Srinivasan, A
Narayanan, SJ
Sridevi, B
Chandrashekar, TK [1 ]
Roy, R
Joshi, BS
机构
[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India
[2] Cent Drug Res Inst, Div Med Chem, Lucknow 226001, Uttar Pradesh, India
关键词
D O I
10.1021/ol000251c
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] Synthesis of new meso aryl 30 pi heptaphyrins 2, 3, and 4 is achieved, Spectroscopic studies reveal that 2, 3, and 4 are aromatic and possess an inverted structure.
引用
收藏
页码:3829 / 3832
页数:4
相关论文
共 22 条
  • [1] OCTAPHYRIN-(1.0.1.0.1.0.1.0)
    BRORING, M
    JENDRNY, J
    ZANDER, L
    SCHMICKLER, H
    LEX, J
    WU, YD
    NENDEL, M
    CHEN, JG
    PLATTNER, DA
    HOUK, KN
    VOGEL, E
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (22) : 2515 - 2517
  • [2] 5,10,15,20-TETRAPHENYLSAPPHYRIN - IDENTIFICATION OF A PENTAPYRROLIC EXPANDED PORPHYRIN IN THE ROTHEMUND SYNTHESIS
    CHMIELEWSKI, PJ
    LATOSGRAZYNSKI, L
    RACHLEWICZ, K
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 1995, 1 (01) : 68 - 73
  • [3] Expanded porphyrins and their heterologs
    Jasat, A
    Dolphin, D
    [J]. CHEMICAL REVIEWS, 1997, 97 (06) : 2267 - 2340
  • [4] Lash TD, 2000, ANGEW CHEM INT EDIT, V39, P1763, DOI 10.1002/(SICI)1521-3773(20000515)39:10<1763::AID-ANIE1763>3.0.CO
  • [5] 2-3
  • [6] Conjugated macrocycles related to the porphyrins. 12. Oxybenzi- and oxypyriporphyrins: Aromaticity and conjugation in highly modified porphyrinoid structures
    Lash, TD
    Chaney, ST
    Richter, DT
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (24) : 9076 - 9088
  • [7] Novel core-modified expanded porphyrins with meso-aryl substituents:: Synthesis, spectral and structural characterization
    Narayanan, SJ
    Sridevi, B
    Chandrashekar, TK
    Vij, A
    Roy, R
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (39) : 9053 - 9068
  • [8] Narayanan SJ, 1998, ANGEW CHEM INT EDIT, V37, P3394, DOI 10.1002/(SICI)1521-3773(19981231)37:24<3394::AID-ANIE3394>3.0.CO
  • [9] 2-4
  • [10] Core-modified smaragdyrins: First examples of stable meso-substituted expanded corrole
    Narayanan, SJ
    Sridevi, B
    Chandrashekar, TK
    Englich, U
    Ruhlandt-Senge, K
    [J]. ORGANIC LETTERS, 1999, 1 (04) : 587 - 590