Modification of the sorptive characteristics of sugarcane bagasse for removing lead from aqueous solutions

被引:96
作者
Angeles Martin-Lara, Maria [1 ]
Rodriguez Rico, Ivan Leandro [2 ]
Aloma Vicente, Ines de la Caridad [2 ]
Blazquez Garcia, Gabriel [1 ]
Calero de hoces, Monica [1 ]
机构
[1] Univ Granada, Dept Chem Engn, E-18071 Granada, Spain
[2] Cent Univ Marta Abreu Las Villas, Santa Clara, Villa Clara, Cuba
关键词
Biosorption; Bagasse; Potentiometric titrations; Wastewater treatment; Lead; HEAVY-METAL REMOVAL; ISOLATED CELL-WALLS; OLIVE POMACE; WASTE-WATER; IONS; BIOSORPTION; ADSORPTION; KINETICS; EQUILIBRIUM; CHROMIUM;
D O I
10.1016/j.desal.2010.02.015
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Bagasse from sugarcane, a waste material, has been studied as a biosorbent for removing lead from aqueous solutions in batch systems. In this study. bagasse was modified by sulphuric acid to enhance sorption capacity for lead and the origin of the enhancement was investigated by observing the change in surface functional group concentrations and the lead sorption behaviours. The untreated and treated bagasse was characterized by elemental analysis, SEM, FTIR and potentiometric titrations. Titrations revealed two different types of sites present on both solid wastes that probably correspond to carboxyl and amine groups. Sorption isotherm test showed that equilibrium sorption data were better represented by Langmuir model than the Freundlich model. The sorption capacities for lead of untreated bagasse and bagasse treated by H2SO4 were 6.366 and 7.297 mg/g, respectively at 25 degrees C and pH 5. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:58 / 63
页数:6
相关论文
共 46 条
[1]   Removal of Cu(II) ions by activated poplar sawdust (Samsun Clone) from aqueous solutions [J].
Acar, Filiz Nuran ;
Eren, Zeynep .
JOURNAL OF HAZARDOUS MATERIALS, 2006, 137 (02) :909-914
[2]   Adsorption studies on Citrus reticulata (fruit peel of orange):: removal and recovery of Ni(II) from electroplating wastewater [J].
Ajmal, M ;
Rao, RAK ;
Ahmad, R ;
Ahmad, J .
JOURNAL OF HAZARDOUS MATERIALS, 2000, 79 (1-2) :117-131
[3]  
Babarinde NAA, 2006, INT J PHYS SCI, V1, P23
[4]   The effect of pH on the biosorption of Cr (III) and Cr (VI) with olive stone [J].
Blazquez, G. ;
Hernainz, F. ;
Calero, M. ;
Martin-Lara, M. A. ;
Tenorio, G. .
CHEMICAL ENGINEERING JOURNAL, 2009, 148 (2-3) :473-479
[5]   Study of Cr (III) biosorption in a fixed-bed column [J].
Calero, M. ;
Hernainz, F. ;
Blazquez, G. ;
Tenorio, G. ;
Martin-Lara, M. A. .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 171 (1-3) :886-893
[6]   BIOSORPTION KINETICS OF Cd (II), Cr (III) AND Pb (II) IN AQUEOUS SOLUTIONS BY OLIVE STONE [J].
Calero, M. ;
Hernainz, F. ;
Blazquez, G. ;
Martin-Lara, M. A. ;
Tenorio, G. .
BRAZILIAN JOURNAL OF CHEMICAL ENGINEERING, 2009, 26 (02) :265-273
[7]  
Demirbas E, 2004, WATER SA, V30, P533
[8]   Modeling and optimization of the dilute-sulfuric-acid pretreatment of corn stover, poplar and switchgrass [J].
Esteghlalian, A ;
Hashimoto, AG ;
Fenske, JJ ;
Penner, MH .
BIORESOURCE TECHNOLOGY, 1997, 59 (2-3) :129-136
[9]   A chemical equilibrium model for metal adsorption onto bacterial surfaces [J].
Fein, JB ;
Daughney, CJ ;
Yee, N ;
Davis, TA .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1997, 61 (16) :3319-3328
[10]   Contribution of sulfonate groups and alginate to heavy metal biosorption by the dry biomass of Sargassum fluitans [J].
Fourest, E ;
Volesky, B .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1996, 30 (01) :277-282