Synthesis of the first complex with a hypercoordinate ylidic carbon atom. Crystal and molecular structure of [{Au(PPh(3))}4CS(=O)Me(2)](ClO4)(2)

被引：49

作者：

Vicente, J ^{[1
]}

Chicote, MT ^{[1
]}

Guerrero, R ^{[1
]}

Jones, PG ^{[1
]}

机构：

[1] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG, INST ANORGAN & ANALYT CHEM, D-38023 BRAUNSCHWEIG, GERMANY

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1996年 / 118卷 / 03期

基金：

日本学术振兴会;

关键词：

D O I：

10.1021/ja953504j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[No abstract available]

引用

页码：699 / 700

页数：2

共 22 条

[1] HYPERCOORDINATE CARBON IN TRIGOLDBIS(SILYL)METHANIUM CATIONS [J].

BOMMERS, S ;

BERUDA, H ;

DUFOUR, N ;

PAUL, M ;

SCHIER, A ;

SCHMIDBAUR, H .

CHEMISCHE BERICHTE, 1995, 128 (02) :137-142

[2] DIMETHYLOXOSULFONIUM METHYLIDE ((CH3)2SOCH2) AND DIMETHYLSULFONIUM METHYLIDE ((CH3)2SCH2) FORMATION AND APPLICATION TO ORGANIC SYNTHESIS [J].

COREY, EJ ;

CHAYKOVSKY, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (06) :1353-+

[3] HYPERCOORDINATE CARBON IN BIS(TRIMETHYLSILYL)TRIS[(TRIPHENYLPHOSPHINE)AURIO(I)]METHANIUM TETRAFLUOROBORATE [J].

DUFOUR, N ;

SCHIER, A ;

SCHMIDBAUR, H .

ORGANOMETALLICS, 1993, 12 (07) :2408-2410

[4]

JOHNSON AW, 1993, YLIDES IMINES PHOSPH

[5] THE COORDINATION CHEMISTRY OF YLIDES [J].

KASKA, WC .

COORDINATION CHEMISTRY REVIEWS, 1983, 48 (01) :1-58

[6] SYNTHESIS OF BINUCLEAR AND TETRANUCLEAR SULFUR YLIDE COMPLEXES OF GOLD(I) BY PHASE-TRANSFER-CATALYSIS TECHNIQUES [J].

LIN, IJB ;

LIU, CW ;

LIU, LK ;

WEN, YS .

ORGANOMETALLICS, 1992, 11 (04) :1447-1449

[7] SYNTHESIS, STRUCTURE, AND BONDING OF THE CATION [(C6H5)3PAU)5C]+ [J].

SCHERBAUM, F ;

GROHMANN, A ;

MULLER, G ;

SCHMIDBAUR, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (04) :463-465

[8] AUROPHILICITY AS A CONSEQUENCE OF RELATIVISTIC EFFECTS - THE HEXAKIS(TRIPHENYLPHOSPHANEAURIO)METHANE DICATION [(PH3PAU)6C]2+ [J].

SCHERBAUM, F ;

GROHMANN, A ;

HUBER, B ;

KRUGER, C ;

SCHMIDBAUR, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (11) :1544-1546

[9] USE OF THE CH ACIDITY OF 2,4,4-TRIMETHYL-4,5-DIHYDROOXAZOLE TO SYNTHESIZE TRIAURIOMETHANES AND NOVEL GOLD CLUSTERS [J].

SCHERBAUM, F ;

HUBER, B ;

MULLER, G ;

SCHMIDBAUR, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (11) :1542-1544

[10] SOME NEW CONCEPTS IN THE CHEMISTRY OF THE P-BLOCK ELEMENTS [J].

SCHMIDBAUR, H .

PURE AND APPLIED CHEMISTRY, 1993, 65 (04) :691-698

← 1 2 3 →