Desulphurization of organic sulphur from coal by electron transfer process with Co2+ ion

This paper reports the results of desulphurization of organic sulphur from a subbituminous Meghalaya coal by the electron transfer process accomplished with the metal ion Co2+. The process was studied both in presence and absence of naphthalene which is used as an electron transfer agent. Temperature dependence on desulphurization unfolded that as the temperature is raised from 25 to 50 degreesC, there is increase in desulphurization performance. Model organic sulphur compounds study revealed that the desulphurization process is effective with aliphatic type of compounds. Infrared spectroscopic study revealed the release of easily removable sulphur compounds as the band intensities due to -S=O and -SO2 groups have declined considerably in their respective regions in the desulphurized coals. The degree of desulphurization is 28.5 wt.% in the presence of naphthalene and 24.6 wt.% in absence of naphthalene, both at 4 h and 50 degreesC. The sulphur extrusion process is continuous and application of a first-order kinetic model produced specific rate constants of the desulphurization reaction in the two systems, at different temperatures, which falls in the range of (1.3-2.9) x 10(-5) s(-1). The activation energy of the sulphur-loss reaction in the system containing naphthalene (26.8 kJ mol(-1)) is about 12% lower than that of the system without naphthalene (30.6 kJ mol(-1)). The frequency factor of the sulphur removal reaction in the systems have been found to be in the range of 0.8-3.2 s(-1), suggesting low amount of successful collisions and an associated type of reaction. The desulphurization reaction is nonspontaneous in nature, proceeds with the absorption of heat and there is reduction in the degree of disorderliness in the system as predicted by the transition state theory. (C) 2004 Published by Elsevier B.V.