Syntheses of L-threose and D-erythrose analogues modified at position 2

被引：26

作者：

André, C ^{[1
]}

Bolte, J ^{[1
]}

Demuynck, C ^{[1
]}

机构：

[1] Univ Blaise Pascal, Dept Chim, UMR 6504 SEESIB, F-63177 Clermont Ferrand, France

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 08期

关键词：

D O I：

10.1016/S0957-4166(98)00126-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

2-O-Methyl-D-erythrose, 2-O-methyl-L-threose, 2-deoxy-D- and L-erythrose, and the corresponding acetonides have been prepared from the commercially available D-isoascorbic and L-ascorbic acids. The proportion of cyclic (alpha and beta furanoses) and acyclic (aldehyde and hydrate) forms was determined in aqueous (D2O) solution by H-1 and C-13 NMR spectroscopy. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1359 / 1367

页数：9

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