Oxidatively induced carbonylation and cyclization of ruthenium(II) vinyl-olefin complexes prepared via allyl/alkyne coupling

被引：14

作者：

Older, CM ^{[1
]}

Stryker, JM ^{[1
]}

机构：

[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 17期

关键词：

D O I：

10.1021/om000407c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

One-electron. oxidation. of otherwise unreactive ((1:4,5-eta)-1,4-pentadien-1-yl)ruthenium carbonyl complexes in acetonitrile under carbon monoxide Leads to the formation of 5-methylene-2-cyclopenten-1-ones via carbonylation, migratory cyclization, and beta-hydride elimination. Oxidation in dichloromethane produces an acyclic 1,4-pentadiene, even under a carbon monoxide atmosphere.

引用

页码：3266 / 3268

页数：3

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