Oxidation of [Ir(η 5-C5Me5)(C3S5)] [C3S52-=4,5-disulfanyl-1,3-dithiole-2-thionate(2-)] and X-ray crystal structure of [IrBr(η5-C5Me5)(μ-C2S4)IrBr(η-C5Me5)]

被引：11

作者：

Kawabata, K ^{[1
]}

Nakano, M ^{[1
]}

Tamura, H ^{[1
]}

Matsubayashi, G ^{[1
]}

机构：

[1] Osaka Univ, Dept Mol Chem, Grad Sch Engn, Toyonaka, Osaka 5600043, Japan

来源：

INORGANICA CHIMICA ACTA | 2004年 / 357卷 / 15期

基金：

日本学术振兴会;

关键词：

Iridium(III) complexes; dithiolate complexes; X-ray crystal structure; ESR spectra;

D O I：

10.1016/j.ica.2004.06.054

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Ir(eta(5)-C5Me5)(C3S5)] [C3S52- = 4,5-disulfanyl-1,3-dithiole-2-thionate(2-)] was prepared by a reaction of [NMe4](2)[C3S5] with [Ir(eta(5)-C5Me5)Cl-2](2) in ethanol, It was reacted with bromine to afford a paramagnetic species [IrBr(eta(5)-C5Me5)(C3S5)] with the Ir-Br bond and in the one-electron-oxidized state, and a diamagnetic dinuclear species [IrBr(eta(5)-C5Me5)(mu-C2S4)IrBr(eta(5)-C5Me5)]. ESR spectra for the one-electron-oxidized species in solution are discussed. The X-ray crystal structural analysis for the latter complex revealed the geometry consisting of dinuclear IrBr(eta(5)-C5Me5) moieties bridged by the C2S42- ligand. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：4373 / 4378

页数：6

共 50 条

[1] [Ni(dmit)2] salts with supramolecular cation structure [J].

Akutagawa, T ;

Nakamura, T .

COORDINATION CHEMISTRY REVIEWS, 2000, 198 :297-311

[2]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[3]

BACHER AD, 1992, Z NATURFORSCH B, V47, P702

[4] (PENTAMETHYLCYCLOPENTADIENYL)NITROSYL(ETHYLENE)IRIDIUM TETRAFLUOROBORATE, [(ETA-5-C5ME5)IR(NO)(C2H4)][BF4] - SYNTHESIS, CHARACTERIZATION, AND SOME REACTIONS - X-RAY CRYSTAL-STRUCTURES OF THE TITLE COMPOUND AND ITS DERIVATIVES (ETA-5-C5ME5)IR(NO)(CH2CH2OET) AND (ETA-5-C5ME5)2IR2X2(MU-X)(MU-NO) (X=BR, I) [J].

BATCHELOR, RJ ;

EINSTEIN, FWB ;

LOWE, ND ;

PALM, BA ;

YAN, XQ ;

SUTTON, D .

ORGANOMETALLICS, 1994, 13 (05) :2041-2052

[5]

BEURSKENS PT, 1994, DIRDIF94 PATTY

[6] GENESIS OF TETRATHIOOXALATE-LIKE C2S4 AND C2SE4 UNITS - A MULTIFORM EXPERIMENTAL-STUDY AND THE RELEVANT THEORETICAL IMPLICATIONS FOR THE ROLE OF TRANSITION-METAL FRAGMENTS [J].

BIANCHINI, C ;

MEALLI, C ;

MELI, A ;

SABAT, M ;

ZANELLO, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (01) :185-198

[7] PHOTOCHEMISTRY OF THE LUMINESCENT ALKYL COMPLEXES ALKYL(CARBONYL)BIS(TRIARYLPHOSPHINE)(MALEONITRILEDITHIOLATO)IRIDIUM, IRR(CO)(PAR3)(2)(MNT) [J].

BRADLEY, P ;

SUARDI, G ;

ZIPP, AP ;

EISENBERG, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (07) :2859-2868

[8] MOLECULAR-METALS AND SUPERCONDUCTORS DERIVED FROM METAL-COMPLEXES OF 1,3-DITHIOL-2-THIONE-4,5-DITHIOLATE (DMIT) [J].

CASSOUX, P ;

VALADE, L ;

KOBAYASHI, H ;

KOBAYASHI, A ;

CLARK, RA ;

UNDERHILL, AE .

COORDINATION CHEMISTRY REVIEWS, 1991, 110 (01) :115-160

[9] DIMERIC (PENTAMETHYLCYCLOPENTADIENYL)RHODIUM AND (PENTAMETHYLCYCLOPENTADIENYL)IRIDIUM COMPLEXES .5. STRUCTURAL STUDIES ON THE HOMOGENEOUS HYDROGENATION CATALYSTS [(ETA5-C5ME5)IRBR]2(MU-BR)2 AND [(ETA5-C5ME5)IRI]2(MU-I)2 AND SYSTEMATICS IN THE SERIES [(ETA5-C5ME5)IRX]2(MU-X)2 (X = CL, BR, I) [J].

CHURCHILL, MR ;

JULIS, SA .

INORGANIC CHEMISTRY, 1979, 18 (05) :1215-1221

[10] THIOOXALATES - THEIR LIGAND PROPERTIES AND COORDINATION CHEMISTRY [J].

DIETZSCH, W ;

STRAUCH, P ;

HOYER, E .

COORDINATION CHEMISTRY REVIEWS, 1992, 121 :43-130

← 1 2 3 4 5 →