Synthesis and structure of a new reduced isopolyvanadate, [V17O42]4-

被引：33

作者：

Hayashi, Y ^{[1
]}

Fukuyama, K ^{[1
]}

Takatera, T ^{[1
]}

Uehara, A ^{[1
]}

机构：

[1] Kanazawa Univ, Fac Sci, Dept Chem, Kanazawa, Ishikawa 9201192, Japan

来源：

CHEMISTRY LETTERS | 2000年 / 07期

关键词：

D O I：

10.1246/cl.2000.770

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduced heptadecavanadate [V17O42](4-) has been synthesized from [H3V10O28](3-) by the reaction using palladium 1,5-COD complex, and characterized by a single crystal X-ray structure analysis. The structure can be regarded as a fused decavanadate and consists of an arrangement of thirteen edge shared VO6 octahedra and four VO5 square pyramids.

引用

页码：770 / 771

页数：2

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