Process options for converting renewable feedstocks to bioproducts

被引:154
作者
Gallezot, Pierre [1 ]
机构
[1] Inst Rech Catalyse & Environm Lyon, F-69626 Villeurbanne, France
关键词
D O I
10.1039/b615413a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This paper discusses the relative advantages of different process options to convert renewable feedstocks ( carbohydrates, vegetable oils, terpenes and lignocellulosic materials) into valuable chemicals and polymers. Three process options are considered: ( 1) via degraded molecules, ( 2) via platform molecules, ( 3) via one-pot processes. These routes can all be integrated in a biorefinery scheme which maximises the value derived from biomass. These process options are illustrated by selected examples underlining the green chemistry value of process options 2 and 3. Stress is laid on new value chains adapted to biomass composition and on the use of recyclable heterogeneous catalysts that lead to waste minimisation and decrease the processing cost of renewables.
引用
收藏
页码:295 / 302
页数:8
相关论文
共 82 条
[1]   Selective chemo-catalytic oxidation of lactose and/of lactobionic acid towards 1-carboxylactulose (2-keto-lactobionic acid) [J].
Abbadi, A ;
Gotlieb, KF ;
Meiberg, JBM ;
vanBekkum, H .
APPLIED CATALYSIS A-GENERAL, 1997, 156 (01) :105-115
[2]   Selective chemo-catalytic routes for the preparation of beta-hydroxypyruvic acid [J].
Abbadi, A ;
vanBekkum, H .
APPLIED CATALYSIS A-GENERAL, 1996, 148 (01) :113-122
[3]  
Abro S, 1997, STUD SURF SCI CATAL, V108, P539
[4]   Softwood bark pyrolysis oil-PF resols - Part 3. Use of propylene carbonate as resin cure accelerator [J].
Amen-Chen, C ;
Riedl, B ;
Wang, XM ;
Roy, C .
HOLZFORSCHUNG, 2002, 56 (03) :281-288
[5]  
Anastas P. T., 1998, GREEN CHEM THEORY PR, P30
[6]  
[Anonymous], PERSPEKTIVEN NACHWAC
[7]   Selective oxidation of alcohols and aldehydes on metal catalysts [J].
Besson, M ;
Gallezot, P .
CATALYSIS TODAY, 2000, 57 (1-2) :127-141
[8]   CATALYTIC-OXIDATION OF GLUCOSE ON BISMUTH-PROMOTED PALLADIUM CATALYSTS [J].
BESSON, M ;
LAHMER, F ;
GALLEZOT, P ;
FUERTES, P ;
FLECHE, G .
JOURNAL OF CATALYSIS, 1995, 152 (01) :116-121
[9]   Catalytic C,C-bond forming additions to unsaturated fatty compounds [J].
Biermann, U ;
Metzger, JO .
TOPICS IN CATALYSIS, 2004, 27 (1-4) :119-130
[10]   Starch-derived polyols for polymer technologies: preparation by hydrogenolysis on metal catalysts [J].
Blanc, B ;
Bourrel, A ;
Gallezot, P ;
Haas, T ;
Taylor, P .
GREEN CHEMISTRY, 2000, 2 (02) :89-91