New types of polycarbonyls of Co+ formed after interaction of CO with Co-ZSM-5:: An FTIR spectroscopic study

被引：26

作者：

Hadjiivanov, K ^{[1
]}

Tsyntsarski, B

Venkov, T

Daturi, M

Saussey, J

Lavalley, JC

机构：

[1] Bulgarian Acad Sci, Inst Gen & Inorgan Chem, BU-1113 Sofia, Bulgaria

[2] Univ Caen, CNRS, ISMRA, Catalyse & Spectrochim Lab, F-14050 Caen, France

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2003年 / 5卷 / 02期

关键词：

D O I：

10.1039/b210476h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Reduction of Co-ZSM-5 with CO results in the creation of Co+ cations forming Co+(CO)(2) species (bands at 2112 and 2042 cm(-1)) which are converted into Co+(CO)(3) tricarbonyls (2137, 2089 and 2079 cm(-1)) in the presence of CO.

引用

页码：243 / 245

页数：3

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