Kinetics study of the gas-phase reactions of C2F5OC(O)H and n-C3F7OC(O)H with OH radicals at 253-328 K

被引：16

作者：

Chen, L ^{[1
]}

Kutsuna, S ^{[1
]}

Tokuhashi, K ^{[1
]}

Sekiya, A ^{[1
]}

机构：

[1] AIST, Tsukuba, Ibaraki 3058569, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2004年 / 400卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2004.11.019

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The rate constants, k(1) and k(2) for the reactions of C2F5OC(O)H and n-C3F7OC(O)H with OH radicals were measured using an FT-IR technique at 253-328 K. k(1) and k(2) were determined as (9.24 +/- 1.33) x 10(-13) exp[-(1230 +/- 40)/T] and (1.41 +/- 0.26) x 10(-12) exp[-(1260 +/- 50)/T] cm(3) molecule(-1) s(-1). The random errors reported are +/-2 sigma, and potential systematic errors of 10% could add to the k(1) and k(2). The atmospheric lifetimes of C2F5OC(O)H and n-C3F7OC(O)H with respect to reaction with OH radicals were estimated at 3.6 and 2.6 years, respectively. (C) 2004 Elsevier B.V. All rights reserved.

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页码：563 / 568

页数：6

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