Spectroscopy and calculations for 4fN→4fN-15d transitions of lanthanide ions in LiYF4

被引：160

作者：

Reid, MF ^{[1
]}

van Pieterson, L

Wegh, RT

Meijerink, A

机构：

[1] Univ Canterbury, Dept Phys & Astron, Christchurch 1, New Zealand

[2] Univ Utrecht, Debye Inst, NL-3508 TA Utrecht, Netherlands

[3] Philips Res Labs, NL-5656 AA Eindhoven, Netherlands

来源：

PHYSICAL REVIEW B | 2000年 / 62卷 / 22期

关键词：

D O I：

10.1103/PhysRevB.62.14744

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Excitation spectra of transitions between the 4f(N) and 4f(N-1)5d configurations of Ce3+, Pr3+, and Nd3+ in LiYF4 have been measured using UV and VUV synchrotron radiation. Both zero-phonon lines and vibronic bands are observed. The energy levels and transitions intensities an reproduced by a theoretical model that extends established models for the 4f(N) configuration by including crystal-field and spin-orbit interactions for the 5d electron and the Coulomb interaction between the 4f and 5d electrons.

引用

页码：14744 / 14749

页数：6

共 17 条

[1]

ANDRIESSEN J, 1996, P INT C IN SCINT THE, P142

[2] A SYSTEMATIC ANALYSIS OF THE SPECTRA OF THE LANTHANIDES DOPED INTO SINGLE-CRYSTAL LAF3 [J].

CARNALL, WT ;

GOODMAN, GL ;

RAJNAK, K ;

RANA, RS .

JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (07) :3443-3457

[3] Optical and scintillation properties of Ce3+ doped LiYF4 and LiLuF4 crystals [J].

Combes, CM ;

Dorenbos, P ;

vanEijk, CWE ;

Pedrini, C ;

DenHartog, HW ;

Gesland, JY ;

Rodnyi, PA .

JOURNAL OF LUMINESCENCE, 1997, 71 (01) :65-70

[4]

Cowan R D., 1981, The theory of atomic structure and spectra

[5]

Gorller-Walrand C, 1998, HANDB PHYSI, V25, P101, DOI 10.1016/S0168-1273(98)25006-9

[6]

GorllerWalrand C, 1996, HANDB PHYSI, V23, P121, DOI 10.1016/S0168-1273(96)23006-5

[7]

Henderson B., 1989, OPTICAL SPECTROSCOPY

[8] Experimental and theoretical investigations of the 4f2 → 4f5d ground-state and excited-state absorption spectra of Pr3+ in LiYF4 [J].

Laroche, M ;

Doualan, JL ;

Girard, S ;

Margerie, J ;

Moncorgé, R .

JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 2000, 17 (07) :1291-1303

[9] Structure, optical absorption, and luminescence energy calculations of Ce3+ defects in LiBaF3 [J].

Marsman, M ;

Andriessen, J ;

van Eijk, CWE .

PHYSICAL REVIEW B, 2000, 61 (24) :16477-16490

[10]

Meijerink A, 2000, ELEC SOC S, V99, P23

← 1 2 →