Gas-occlusion properties of a novel compound: Mononuclear copper(II) terephthalate-pyridine

被引：26

作者：

Ohmura, T ^{[1
]}

Mori, W ^{[1
]}

Hasegawa, M ^{[1
]}

Takei, T ^{[1
]}

Yoshizawa, A ^{[1
]}

机构：

[1] Kanagawa Univ, Dept Chem, Hiratsuka, Kanagawa 2591293, Japan

来源：

CHEMISTRY LETTERS | 2003年 / 32卷 / 01期

关键词：

D O I：

10.1246/cl.2003.34

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mononuclear copper(II) terephthalate-pyridine, which has a regular one-dimensional structure, occludes large amounts of gases. The maximum amount of N-2 gas that can be occluded by mononuclear copper(II) terephthalate-pyridine is 1.1 mole per mole of copper(II) salt, indicating the presence of a large number of micropores. A porous structure, which is formed by hydrogen bonding and self-assembly of the linear copper(II) terephthalate-pyridine, was determined by X-ray crystallography.

引用

页码：34 / 35

页数：2

共 10 条

[1] Copper(III) benzoate nitroxide dimers and chains: Structure and magnetic studies [J].

Del Sesto, RE ;

Arif, AM ;

Miller, JS .

INORGANIC CHEMISTRY, 2000, 39 (21) :4894-4902

[2] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

[3] METHOD FOR THE CALCULATION OF EFFECTIVE PORE-SIZE DISTRIBUTION IN MOLECULAR-SIEVE CARBON [J].

HORVATH, G ;

KAWAZOE, K .

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1983, 16 (06) :470-475

[4] Solvothermal synthesis of a stable coordination polymer with copper-I-copper-II dimer units:: [Cu4{1,4-C6H4(COO)2}3(4,4′-bipy)2]n [J].

Lo, SMF ;

Chui, SSY ;

Shek, LY ;

Lin, ZY ;

Zhang, XX ;

Wen, GH ;

Williams, ID .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (26) :6293-6294

[5] Synthesis of new adsorbent copper(II) terephthalate [J].

Mori, W ;

Inoue, F ;

Yoshida, K ;

Nakayama, H ;

Takamizawa, S ;

Kishita, M .

CHEMISTRY LETTERS, 1997, (12) :1219-1220

[6] Framework engineering by anions and porous functionalities of Cu(II)/4,4′-bpy coordination polymers [J].

Noro, S ;

Kitaura, R ;

Kondo, M ;

Kitagawa, S ;

Ishii, T ;

Matsuzaka, H ;

Yamashita, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (11) :2568-2583

[7] New microporous coordination polymer affording guest-coordination sites at channel walls [J].

Noro, S ;

Kitagawa, S ;

Yamashita, M ;

Wada, T .

CHEMICAL COMMUNICATIONS, 2002, (03) :222-223

[8] The gas-occlusion properties of dicarboxylate (fumarate, trans-trans-muconate and terephthalate) ruthenium(II,III) dinuclear complexes [J].

Takamizawa, S ;

Yamaguchi, K ;

Mori, W .

INORGANIC CHEMISTRY COMMUNICATIONS, 1998, 1 (05) :177-178

[9] Synthesis and gas-occlusion properties of dinuclear molybdenum(II) dicarboxylates (fumarate, terephthalate, trans-trans-muconate, pyridine-2,5-dicarboxylate, and trans-1,4-cyclohexanedicarboxylate) [J].

Takamizawa, S ;

Mori, W ;

Furihata, M ;

Takeda, S ;

Yamaguchi, K .

INORGANICA CHIMICA ACTA, 1998, 283 (01) :268-274

[10] Synthesis and gas-occlusion properties of ruthenium(II,III) dicarboxylates (fumarate, trans-trans-muconate and terephthalate) bridged by halogen atoms [J].

Takamizawa, S ;

Ohmura, T ;

Yamaguchi, K ;

Mori, W .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2000, 342 :199-204

← 1 →