Optimal operation of a semi-batch reactive distillation column

被引：26

作者：

Fernholz, G ^{[1
]}

Engell, S ^{[1
]}

Kreul, LU ^{[1
]}

Gorak, A ^{[1
]}

机构：

[1] Univ Dortmund, Dept Chem Engn, D-4600 Dortmund, Germany

来源：

COMPUTERS & CHEMICAL ENGINEERING | 2000年 / 24卷 / 2-7期

关键词：

optimization; reactive distillation; batch distillation; optimal operation;

D O I：

10.1016/S0098-1354(00)00553-6

中图分类号：

TP39 [计算机的应用];

学科分类号：

081203 ; 0835 ;

摘要：

By using reactive distillation processes, limitations due to reaction equilibria and due to azeotropes can be overcome, resulting in an intensified overall process. We here present work on the optimization of a semi-batch process, the heterogeneously catalyzed esterification of methanol and acetic acid. Two different cost functions, minimal batch time and maximal productivity of the process are compared. Constraints are added to ensure the purity of the product and sufficient conversion of the raw materials. The analysis of the influence of the prescribed conversion rates on the productivity helps to detect the crucial parameters of the optimization problem, giving deeper insight into the process. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：1569 / 1575

页数：7

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