A hexaallyl[C60]fullerene, C60(CH2CH=CH2)6

被引:23
作者
Abdul-Sada, AK [1 ]
Avent, AG [1 ]
Birkett, PR [1 ]
Kroto, HW [1 ]
Taylor, R [1 ]
Walton, DRM [1 ]
机构
[1] Univ Sussex, Fullerene Sci Ctr, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1998年 / 03期
关键词
D O I
10.1039/a708197i
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
C60Cl6 Reacts with allyltrimethylsilane in the presence of TiCl4 to form a C-S symmetrical, hexaallyl addended [60]fullerene derivative, C-60(CH2CH=CH2)(6), in 58% yield; C-60(CH2CH=CH2)(5)Cl is separated as a minor reaction product in 14% yield.
引用
收藏
页码:393 / 395
页数:3
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