Time-resolved UPS: a new experimental technique for the study of surface chemical reactions on femtosecond time-scales

被引:11
作者
Bauer, M [1 ]
Lei, C [1 ]
Tobey, R [1 ]
Murnane, MM [1 ]
Kapteyn, H [1 ]
机构
[1] Univ Kaiserslautern, Fachbereich Phys, Dept Phys, D-67663 Kaiserslautern, Germany
关键词
visible and ultraviolet photoelectron spectroscopy; surface chemical reaction; oxygen; platinum;
D O I
10.1016/S0039-6028(03)00414-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recent progress in the generation of ultrashort XUV-pulses by means of high harmonic generation provides a means to monitor the dynamics of surface chemical reactions using photoemission spectroscopy. In this paper we describe details of an experimental setup for time-resolved photoemission spectroscopy using high harmonic generation. We also present results where the different steps involved in the laser-induced change of, an adsorbate-surface bond were monitored with sub-100 femtosecond time-resolution. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:1159 / 1165
页数:7
相关论文
共 15 条
[1]  
Anisimov S. I., 1975, SOV PHYS JETP, V39, P375, DOI DOI 10.1016/J.JMATPROTEC.2009.05.031
[2]   Direct observation of surface chemistry using ultrafast soft-x-ray pulses [J].
Bauer, M ;
Lei, C ;
Read, K ;
Tobey, R ;
Gland, J ;
Murnane, MM ;
Kapteyn, HC .
PHYSICAL REVIEW LETTERS, 2001, 87 (02) :1-025501
[3]   DYNAMICS OF NONTHERMAL REACTIONS - FEMTOSECOND SURFACE-CHEMISTRY [J].
CAVANAGH, RR ;
KING, DS ;
STEPHENSON, JC ;
HEINZ, TF .
JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (04) :786-798
[4]   INNER VALENCE LEVELS AS A STRUCTURAL PROBE FOR CHEMISORBED MOLECULES - O-2 ON PT(111) [J].
EBERHARDT, W ;
UPTON, T ;
CRAMM, S ;
INCOCCIA, L .
CHEMICAL PHYSICS LETTERS, 1988, 146 (06) :561-565
[5]   ELECTRON THERMALIZATION IN GOLD [J].
FANN, WS ;
STORZ, R ;
TOM, HWK ;
BOKOR, J .
PHYSICAL REVIEW B, 1992, 46 (20) :13592-13595
[6]   RESONANCE-ASSISTED, HOT-ELECTRON-INDUCED DESORPTION [J].
GADZUK, JW .
SURFACE SCIENCE, 1995, 342 (1-3) :345-358
[7]   Photoemission with laser-generated harmonics tunable to 80 eV [J].
Haight, R .
APPLIED OPTICS, 1996, 35 (33) :6445-6448
[8]  
Hufner S., 1995, Photoelectron Spectroscopy, VVolume 82
[9]  
Palik E., 1986, HDB OPTICAL CONSTANT
[10]   PHYSISORBED, CHEMISORBED AND DISSOCIATED O-2 ON PT(111) STUDIED BY DIFFERENT CORE-LEVEL SPECTROSCOPY METHODS [J].
PUGLIA, C ;
NILSSON, A ;
HERNNAS, B ;
KARIS, O ;
BENNICH, P ;
MARTENSSON, N .
SURFACE SCIENCE, 1995, 342 (1-3) :119-133