A nonflammable lithium polymer battery with high performance for elevated temperature applications

被引:11
作者
Bakenov, Zhumabay [1 ]
Nakayama, Masanobu [1 ]
Wakihara, Masataka [1 ]
机构
[1] Tokyo Inst Technol, Dept Appl Chem, Meguro Ku, Tokyo 1528552, Japan
关键词
D O I
10.1149/1.2750229
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
All- solid Li/ LiFePO4 lithium polymer batteries with nonflammable poly (ethylene glycol) borate ester- based polymer electrolyte have been constructed and successfully operated at ambient and elevated temperatures. The cell exhibited about 90% of the theoretical capacity at 0.1 C rate at 60 degrees C. The AlPO4 addition to the polymer electrolyte improved the Li/ LiFePO4 polymer cell rate performance and allowed stable prolonged cycling even at 2 C rate at 60 degrees C. The ac impedance spectroscopy data showed the electrode/ electrolyte interface stabilization and lowering of cell impedance in the presence of AlPO4. (c) 2007 The Electrochemical Society.
引用
收藏
页码:A208 / A211
页数:4
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