Thermodynamics of solvent extraction

被引：82

作者：

Choppin, GR ^{[1
]}

Morgenstern, A ^{[1
]}

机构：

[1] Florida State Univ, Tallahassee, FL 32306 USA

来源：

SOLVENT EXTRACTION AND ION EXCHANGE | 2000年 / 18卷 / 06期

关键词：

D O I：

10.1080/07366290008934721

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The fundamental thermodynamic characteristics of aqueous electrolyte solutions and organic solutions which affect solvent extraction are summarized and the influence of metal complexation and hydration on the distribution ratios is discussed. The thermodynamics of extraction systems, including synergistic systems, is reviewed. The influence of structural aspects of the complexing extractant agents on these thermodynamic parameters is also reviewed.

引用

页码：1029 / 1049

页数：21

共 12 条

[1]

ALLARD B, 1992, SYSTEMATIC SOLVENT E, pCH3

[2]

[Anonymous], 1985, ION SOLVATION

[3]

CHOPPIN GR, 1992, COMPLEXATION METAL I, pCH3

[4]

GRENTHE, 1991, CHEM THERMODYNAMICS