(4R,5R)-bis(N,N-dimethylaminocarbonyl)-2-chloro-1,3,2-dioxaphospholane:: a convenient reagent for control of enantiomeric composition of chiral alcohols by 31P NMR spectroscopy

被引：8

作者：

Bredikhin, AA ^{[1
]}

Strunskaya, EI ^{[1
]}

Azancheev, NM ^{[1
]}

Bredikhina, ZA ^{[1
]}

机构：

[1] Russian Acad Sci, AE Arbuzov Organ & Phys Chem Inst, Kazan Res Ctr, Kazan 420083, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1998年 / 47卷 / 01期

关键词：

chiral alcohols; enantiomeric composition; P-31 NMR spectroscopy;

D O I：

10.1007/BF02495528

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of enantiomerically pure cyclic chlorophosphite obtained by the reaction of PCl3 with N,N,N',N'-tetramethyldiamide of natural L-(+)-tartaric acid for analysis of the enantiomeric composition of chiral primary and secondary alcohols by P-31 NMR spectroscopy is considered.

引用

页码：174 / 176

页数：3

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