Topochemical oxygen deintercalation in oxides using butyllithium

被引：1

作者：

Badri, V ^{[1
]}

Wang, YT ^{[1
]}

Hermann, AM ^{[1
]}

机构：

[1] Univ Colorado, Dept Phys, Boulder, CO 80309 USA

来源：

PHYSICA C | 2000年 / 339卷 / 02期

关键词：

D O I：

10.1016/S0921-4534(00)00331-2

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Topochemical oxygen deintercalation in oxides has been carried out using n-butyllithium as a mild reducing agent. Compounds such as La2CuO4+delta and Tl2Ba2CuO6+delta can be conveniently reduced to a desirable oxygen content phase. However, n-butyllithium does not remove the strongly bound lattice oxygen from the structure maintaining the integrity of the structure. The results of the various oxide phases studied are reported in this paper. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：106 / 112

页数：7

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