Syntheses of optically active polyacrylates

被引：3

作者：

Athawale, VD ^{[1
]}

Gaonkar, SR ^{[1
]}

机构：

[1] Univ Mumbai, Dept Chem, Mumbai 400098, India

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY | 1998年 / A35卷 / 06期

关键词：

lipase; acrylate; transesterification; resolution; optically active;

D O I：

10.1080/10601329808002025

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Different secondary alcohols were resolved by lipase catalyzed transesterification using 2,3-butanedione monoxime acrylate as acrylating agent. The results showed that the reaction rates were the fastest among reactions reported until now. The effect of solvent on the transesterification rate was studied. The enantiomeric excess (ee) and enantiomeric purity (E value) of all the acrylate monomers were determined. The synthesized optically active acrylate monomers were polymerized by free radical polymerization technique.

引用

页码：985 / 1001

页数：17

共 13 条

[1]

[Anonymous], [No title captured]

[2] GENERAL-ASPECTS AND OPTIMIZATION OF ENANTIOSELECTIVE BIOCATALYSIS IN ORGANIC-SOLVENTS - THE USE OF LIPASES [J].