Electrophoretic co-deposition of PEEK-hydroxyapatite composite coatings for biomedical applications

被引:90
作者
Bastan, Fatih E. [1 ,2 ]
Rehman, Muhammad Atiq Ur [2 ]
Avcu, Yasemin Yildiran [2 ,3 ]
Avcu, Egemen [2 ,4 ]
Ustel, Fatih [1 ]
Boccaccin, Aldo R. [2 ]
机构
[1] Sakarya Univ, Fac Engn, Dept Met & Mat Engn, Thermal Spray Res & Dev Lab, TR-54187 Esentepe, Sakarya, Turkey
[2] Univ Erlangen Nurnberg, Inst Biomat, Cauerstr 6, D-91058 Erlangen, Germany
[3] Kocaeli Univ, Fac Engn, Dept Mech Engn, TR-41380 Kocaeli, Turkey
[4] Kocaeli Univ, Ford Otosan Ihsaniye Automot Vocat Sch, Machine & Met Technol, TR-41680 Kocaeli, Turkey
关键词
Electrophoretic deposition; EPD; Co-deposition; Composite coating; Hydroxyapatite; PEEK; IN-VITRO BIOACTIVITY; POLYETHERETHERKETONE PEEK; ORTHOPEDIC IMPLANTS; STAINLESS-STEEL; DEPOSITION; ADHESION; SURFACE; POLY(ETHERETHERKETONE); OSSEOINTEGRATION; BIOCOMPATIBILITY;
D O I
10.1016/j.colsurfb.2018.05.005
中图分类号
Q6 [生物物理学];
学科分类号
071011 [生物物理学];
摘要
This study focuses on the optimization of electrophoretic deposition (EPD) and suspension parameters for producing PEEK-hydroxyapatite (HA) coatings with feasible microstructure, adhesion strength, and in-vitro bioactivity. Nanostructured hydroxyapatite (HA) micro-granules were incorporated with PEEK to form PEEK-hydroxyapatite composite coatings via EPD. After EPD, a heat-treatment at 375 degrees C was applied for densification of the coatings and for enhancing the adhesion between the coatings and the substrates. It was found that both adhesion strength and in-vitro bioactivity of the coatings were dependent on the PEEK and HA relative contents. Thus, increasing the amount of HA improved the bioactivity while decreased the adhesion strength of the coatings. Apatite-like layer formation was observed on coatings with high HA content after incubation for three days in simulated body fluid (SBF). Finally, a deposition mechanism was proposed for the EPD of the PEEK-hydroxyapatite composite system. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:176 / 182
页数:7
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