Novel chiral "calixsalen" macrocycle and chiral Robson-type macrocyclic complexes

被引：79

作者：

Gao, J

Reibenspies, JH

Zingaro, RA

Woolley, FR

Martell, AE

Clearfield, A

机构：

[1] Univ Texas, Hlth Sci Ctr, Dept Radiol, San Antonio, TX 78229 USA

[2] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 02期

关键词：

D O I：

10.1021/ic049181m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A family of novel chiral "calixsalen" Schiff base macrocycles R,R-H(3)L4, R,R-H(3)L5, containing three chiral diamino moieties were synthesized by an efficient self-assembly and characterized by H-1 and C-13 NMR, mass spectrometry, and X-ray diffraction. The systematic synthesis, structure, and coordination properties of the [2 + 2] and [3 + 3] Robson-type Schiff base macrocyclic mono-, di-, tri-, and tetranuclear metal complexes were explored.

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页码：232 / 241

页数：10

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