Complexes of bismuth(III) chloride with oxygen donor ligands. Structural characterization of BiCl3 center dot 3THF, BiCl3 diglyme and BiCl3 center dot diethylcarbitol

被引：27

作者：

Eveland, JR ^{[1
]}

Whitmire, KH ^{[1
]}

机构：

[1] RICE UNIV,DEPT CHEM,HOUSTON,TX 77251

来源：

INORGANICA CHIMICA ACTA | 1996年 / 249卷 / 01期

关键词：

crystal structures; bismuth complexes; chloride complexes; oxygen donor ligand complexes;

D O I：

10.1016/0020-1693(96)05024-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The bismuth(III) chloride ether complexes BiCl3 . diglyme (1), BiCl3 . diethylcarbitol (2) and BiCl3 . 3THF (3) (diglyme = bis(2-methoxy)ethyl ether; diethylcarbitol = bis(2-ethoxy)ethyl ether) have been prepared. Compounds 1 and 2 form dimers in the solid state and exhibit distorted pentagonal bipyramidal coordination around the bismuth centers, while complex 3 is monomeric in the crystal lattice and shows approximate octahedral coordination for bismuth.

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页码：41 / 46

页数：6

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