Direct carbon fuel cell: Fundamentals and recent developments

被引:343
作者
Cao, Dianxue [1 ]
Sun, Yong [1 ]
Wang, Guiling [1 ]
机构
[1] Harbin Engn Univ, Coll Mat Sci & Chem Engn, Harbin 150001, Peoples R China
关键词
direct carbon fuel cell; carbon electrooxidation; clean coal to electricity technology; ELECTROCHEMICAL OXIDATION; ENERGY;
D O I
10.1016/j.jpowsour.2007.02.034
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The direct carbon fuel cell is a special type of high temperature fuel cell that directly uses solid carbon as anode and fuel. As an electrical power generator for power plants, it has a higher achievable efficiency (80%) than the molten carbonate and solid oxide fuel cells, and has less emissions than conventional coal-burning power plants. More importantly, its solid carbon-rich fuels (e.g. coal, biomass, organic garbage) are readily available and abundant. In this review, some fundamental study results of electrochemical oxidation of carbon in molten salts are summarized. Recent developments in direct carbon fuel cell configurations and performance are also discussed. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:250 / 257
页数:8
相关论文
共 51 条
[1]  
BALACHOV LL, 2005, FUEL CELL SEM DIR CA
[2]  
Baur E, 1933, Z ELKTROCHEM ANGEW P, V39, P169
[3]   Direct conversion of carbon fuels in a molten carbonate fuel cell [J].
Cherepy, NJ ;
Krueger, R ;
Fiet, KJ ;
Jankowski, AF ;
Cooper, JF .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (01) :A80-A87
[4]  
CHUANG SSC, 2005, FUEL CELL SEM DIR CA
[5]  
COOPER JF, 2004, Patent No. 2004229109
[6]  
Cooper JF, 2005, US patent, Patent No. [6, 878, 479, 6878479]
[7]  
Cooper JF, 2003, DIR CARB FUEL CELL W
[8]  
Cooper JF, 2005, FUEL CELL SEM DIR CA
[9]  
COOPER JF, 2005, Patent No. 2005066573
[10]  
COOPER JF, 2005, Patent No. 2005066574