Solution- and solid-state characterisation of a configurationally-stable β-diketiminato-supported calcium primary amide

被引：32

作者：

Avent, AG

Crimmin, MR

Hill, MS

Hitchcock, PB

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

[2] Univ Sussex, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

DALTON TRANSACTIONS | 2004年 / 20期

关键词：

D O I：

10.1039/b412060d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

'Selective' protonolysis of the beta-diketiminato calcium derivative [Ca{(NDippCMe)(2)CH}{N(SiMe3)(2)}(THF)] (Dipp=(C6H3Pr2)-Pr-i-2,6) with H2N(CH2)(2)OCH3 produced the dimeric species [Ca{(NDippCMe)(2)CH}{mu-NH(CH2)(2)OMe}](2), which has been fully characterised in solution and in the solid state.

引用

页码：3166 / 3168

页数：3

共 23 条

[1]

Alexander JS, 2002, EUR J INORG CHEM, P2761

[2]

AVENT AG, UNPUB DALTON T

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