Facile solid-state synthesis of highly conducting poly(ethylenedioxythiophene)

被引：140

作者：

Meng, H

Perepichka, DF

Wudl, F ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

[2] Univ Calif Los Angeles, Exot Mat Inst, Los Angeles, CA 90095 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 06期

关键词：

C-C coupling; conducting materials; polymerization; polythiophenes; solidstate reactions;

D O I：

10.1002/anie.200390181

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Gentle heating of crystalline 2,5-dibromo-3,4-ethylenedioxythiophene affords a highly conducting, bromine-doped poly (3,4-ethylenedioxythiophene) (PEDOT). The conductivity of the polymer can be further increased by doping with iodine. By using this approach, thin films of PEDOT with a conductivity as high as 20 Scm-1 can be easily fabricated on insulating plastic surfaces (see picture).

引用

页码：658 / 661

页数：4

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