High resolution study of the Β1Π-Χ1Σ+ band system of KLi and the isotopic effect

被引：13

作者：

Jastrzebski, W

Kowalczyk, P

机构：

[1] Polish Acad Sci, Inst Phys, PL-02668 Warsaw, Poland

[2] Univ Warsaw, Inst Expt Phys, PL-00681 Warsaw, Poland

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1998年 / 54卷 / 03期

关键词：

Doppler-free spectroscopy; high resolution; isotopic effect;

D O I：

10.1016/S1386-1425(97)00261-8

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The Doppler-free polarization spectrum was measured for the B-1 Pi-X-1 Sigma(+) band system of the (KLi)-K-39-Li-7 molecule. The Dunham coefficients describing the X state and f-parity levels of the B state are reported. Numerous transitions were observed for the (KLi)-K-41-Li-7 and (KLi)-K-39-Li-6 isotopomers, the latter ones displaying anomalous isotopic shifts. The anomalies are discussed in terms of mass-independent 'reduced' Dunham coefficients and mass-scaling factors. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

收藏

页码：459 / 463

页数：5

相关论文

共 12 条

[1]

[Anonymous], 1978, ATLAS SPECTRE ABSORP

[2] Doppler-free spectroscopy of KLi [J].

Bednarska, V ;

Ekers, A ;

Kowalczyk, P ;

Jastrzebski, W .

JOURNAL OF CHEMICAL PHYSICS, 1997, 106 (15) :6332-6337

[3] A three-section heat-pipe oven for heteronuclear alkali molecules [J].

Bednarska, V ;

Jackowska, I ;

Jastrzebski, W ;

Kowalczyk, P .

MEASUREMENT SCIENCE AND TECHNOLOGY, 1996, 7 (09) :1291-1293

[4] NUCLEAR MASS DEPENDENCE OF DUNHAM COEFFICIENTS AND BREAKDOWN OF BORN-OPPENHEIMER APPROXIMATION [J].

BUNKER, PR .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1977, 68 (03) :367-371

[5]

Demtroder W., 1996, LASER SPECTROSCOPY

[6] THE BI-PI-X1-SIGMA+ SYSTEM OF K-39LI-6 AND K-39LI-7 - HIGH-RESOLUTION LASER EXCITATION AND FLUORESCENCE SPECTROSCOPY USING SELECTIVELY DETECTED LASER-INDUCED FLUORESCENCE (SDLIF) IN MOLECULAR-BEAM AND INJECTION HEAT PIPE (IHP) [J].

ENGELKE, F ;

HAGE, H ;

SPRICK, U .

CHEMICAL PHYSICS, 1984, 88 (03) :443-453

[7] ABSOLUTE IODINE (I-2) STANDARDS MEASURED BY MEANS OF FOURIER-TRANSFORM SPECTROSCOPY [J].

GERSTENKORN, S ;

LUC, P .

REVUE DE PHYSIQUE APPLIQUEE, 1979, 14 (08) :791-794

[8]

Herzberg G, 1950, Molecular spectra molecular structure: Spectra of diatomic molecules, VI

[9] CENTRIFUGAL-DISTORTION CONSTANTS FOR DIATOMIC-MOLECULES - AN IMPROVED COMPUTATIONAL METHOD [J].

HUTSON, JM .

JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1981, 14 (05) :851-857

[10] HYPERFINE-STRUCTURE OF THE NAK-C3-SIGMA+ STATE AND THE EFFECTS OF PERTURBATION [J].

ISHIKAWA, K ;

KUMAUCHI, T ;

BABA, M ;

KATO, H .

JOURNAL OF CHEMICAL PHYSICS, 1992, 96 (09) :6423-6432