Selective methanation of CO in hydrogen-rich gases involving large amounts of CO2 over Ru-modified Ni-Al mixed oxide catalysts

被引：65

作者：

Kimura, Masae ^{[2
]}

Miyao, Toshihiro ^{[1
]}

Komori, Shingo ^{[2
]}

Chen, Aihua ^{[1
]}

Higashiyama, Kazutoshi ^{[1
]}

Yamashita, Hisao ^{[1
]}

Watanabe, Masahiro ^{[1
]}

机构：

[1] Univ Yamanashi, Fuel Cell Nanomat Ctr, Kofu, Yamanashi 4000021, Japan

[2] Univ Yamanashi, Interdisciplinary Grad Sch Med & Engn, Kofu, Yamanashi 4008510, Japan

来源：

APPLIED CATALYSIS A-GENERAL | 2010年 / 379卷 / 1-2期

关键词：

Selective CO methanation; Ru-modified Ni-Al mixed oxide catalyst; Hydrogen production; Solution-spray plasma technique; MICROCHANNEL REACTOR; METAL-CATALYSTS; CARBON OXIDES; REMOVAL; TRACE;

D O I：

10.1016/j.apcata.2010.03.021

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Selective methanation of CO was investigated in hydrogen-rich gas streams involving 20% CO2 over a Ru-modified Ni-Al mixed oxide catalyst. The Ni-Al mixed oxide was prepared by the solution-spray plasma technique, by which fine powders of homogeneous mixed oxides can be easily synthesized. By the addition of a small amount of Ru, the catalytic activity and selectivity of the Ni-Al mixed oxide catalyst for CO methanation was improved dramatically. The added Ru enhanced the formation of nano-sized Ni metal particles via reduction of the mixed oxide by spill-over-hydrogen during reduction treatment, even at low temperature. Kinetic measurements revealed that the methanation of CO took place predominantly over the Ni metal sites. Selectivity for the CO methanation was also improved significantly by the addition of Ru due to suppression of CO2 dissociation over the Ni metal sites. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：182 / 187

页数：6

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