Formation of a linear supramolecular polymer by self-assembly of two homoditopic monomers based on the bis(m-phenylene)-32-crown-10/Paraquat recognition motif

被引：128

作者：

Huang, Feihe ^{[1
]}

Nagvekar, Devdatt S.

Zhou, Xiaochuan

Gibson, Harry W.

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

[2] Virginia Polytech Inst & State Univ, Dept Chem, Blacksburg, VA 24601 USA

来源：

MACROMOLECULES | 2007年 / 40卷 / 10期

关键词：

D O I：

10.1021/ma062080i

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A homoditopic monomer containing two bis(m-phenylene)-32-crown-10 units and a complementary homoditopic monomer containing two paraquat moieties were designed and prepared. At high equimolar concentrations (> 40 mM) they self-organize to form a linear supramolecular polymer in solution as confirmed by proton NMR spectroscopy, mass spectrometry, and viscosity studies.

引用

页码：3561 / 3567

页数：7

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