Synthesis and Diels-Alder reactions of 1,2-dimethylene[2.n]metacyclophanes

被引：39

作者：

Yamato, T

Miyamoto, S

Hironaka, T

Miura, Y

机构：

[1] Saga Univ, Fac Sci & Engn, Dept Appl Chem, Saga 8408502, Japan

[2] Kyushu Univ, Ctr Adv Instrumental Anal, Kasuga, Fukuoka 8168510, Japan

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 01期

关键词：

D O I：

10.1021/ol0483403

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Diels-Alder reaction of 1,2-dimethylene[2.n]MCPs (MCP = metacyclophane) with suitable dienophiles followed by aromatization and photoincluced or FeCl3-induced transannular cyclization afforded phenanthrene-anellated polycyclic aromatic hydrocarbons, which were found to adopt helical chirality in the solid state.

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页码：3 / 6

页数：4

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