Synthesis of the neutral (CuF(NC5H5)4)2NbOF5 cluster

被引：16

作者：

Norquist, AJ ^{[1
]}

Welk, ME ^{[1
]}

Stern, CL ^{[1
]}

Poeppelmeier, KR ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

CHEMISTRY OF MATERIALS | 2000年 / 12卷 / 07期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1021/cm0001354

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Composition space diagrams can be used to study the stability and variety of mixed transition metal oxide fluorides prepared under hydro(solvato)thermal conditions. Prior to this work the neutral (CuF(NC5H5)(4))(2)NbOF5 cluster had not been observed but it was expected because of the nucleophilic character of the oxygen and trans fluorine in the [NbOF5](2-) species, [H3O](2)[(CuF(NC5H5)(4))(2)NbOF5][F](2), a compound containing the 2:1 (Cu: Nb) cluster, was synthesized from the concentration variables, [CuO . 0.5 Nb2O5], [(HF), pyridine], and [H2O], by adding a fourth, [pyridine], and extending the composition space from a two-dimensional triangle to a three-dimensional prism. Crystal Data: [H3O](2)[(CuF(NC5H5)(4))(2)NbOF5][F](2), tetragonal, space group I4(1)/acd (no, 142), with a = 24.691(1) Angstrom, c = 14.556(1) Angstrom, Z = 8.

引用

页码：1905 / 1909

页数：5

共 13 条

[1]

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[2]

Beurskens P. T., 1994, DIRDIF 94 PROGRAM SY

[3] STRUCTURE AND VIBRATIONAL-SPECTRA OF OXONIUM HEXAFLUOROARSENATES(V) AND HEXAFLUOROANTIMONATES(V) [J].