Chemically modified β-cyclodextrins:: Efficient supramolecular carriers for the biphasic hydrogenation of water-insoluble aldehydes

被引：31

作者：

Monflier, E

Tilloy, S

Castanet, Y

Mortreux, A

机构：

[1] Univ Artois, Fac Sci J Perrin, Lab Physicochim Interfaces & Applicat, F-62307 Lens, France

[2] CNRS, Catalyse Heterogene & Homogene Lab, F-59659 Villeneuve Dascq, France

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 19期

关键词：

D O I：

10.1016/S0040-4039(98)00378-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydrogenation of water-insoluble aldehydes can be achieved in high yields in a genuine two-phase system by using a recoverable catalytic system composed of a water-soluble ruthenium/triphenylphosphine trisulfonate complex and a suitable chemically modified beta-cyclodextrin. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2959 / 2960

页数：2

共 9 条

[1] On the synthesis and characterization of two ruthenium water-soluble complexes: Preliminary results on the hydrogenation of cinnamaldehyde in a biphasic system. Surface activity of the ligands TPPMS and TPPTS
Andriollo, A
Carrasquel, J
Marino, J
Lopez, FA
Paez, DE
Rojas, I
Valencia, N
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 116 (1-2) : 157 - 165
[2] CORNILS B, 1996, APPL HOMOGENEOUS CAT, V2, P577
[3] HOMOGENEOUS CATALYSIS IN WATER .3. THE CATALYTIC-HYDROGENATION OF PROPIONALDEHYDE WITH (RUCL2L2)2, RUHCLL3, RUH(OAC)L3, RUH2L4, RUHIL3, RUCL2(CO)2L2 AND [RU(OAC)(CO)2L]2, (L=P(C6H4-MSO3NA)3.3H2O) - A KINETIC INVESTIGATION OF THE SALT EFFECT IN WATER
FACHE, E
SANTINI, C
SENOCQ, F
BASSET, JM
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1992, 72 (03): : 337 - 350
[4] SELECTIVE HYDROGENATION OF ALPHA,BETA-UNSATURATED ALDEHYDES CATALYZED BY SUPPORTED AQUEOUS-PHASE CATALYSTS AND SUPPORTED HOMOGENEOUS CATALYSTS
FACHE, E
MERCIER, C
PAGNIER, N
DESPEYROUX, B
PANSTER, P
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1993, 79 (1-3): : 117 - 131
[5] SELECTIVE HYDROGENATION OF ALPHA,BETA-UNSATURATED ALDEHYDES IN AQUEOUS ORGANIC 2-PHASE SOLVENT SYSTEMS USING RUTHENIUM OR RHODIUM COMPLEXES OF SULFONATED PHOSPHINES
GROSSELIN, JM
MERCIER, C
ALLMANG, G
GRASS, F
[J]. ORGANOMETALLICS, 1991, 10 (07) : 2126 - 2133
[6] Study of the hydrogenation of alpha,beta-unsaturated carbonyl compounds catalyzed by water-soluble ruthenium-TPPTS complexes
Hernandez, M
Kalck, P
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 116 (1-2) : 131 - 146
[7] WACKER OXIDATION OF 1-DECENE TO 2-DECANONE IN THE PRESENCE OF A CHEMICALLY-MODIFIED CYCLODEXTRIN SYSTEM - A HAPPY UNION OF HOST-GUEST CHEMISTRY AND HOMOGENEOUS CATALYSIS
MONFLIER, E
BLOUET, E
BARBAUX, Y
MORTREUX, A
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (20): : 2100 - 2102
[8] MOLECULAR RECOGNITION BETWEEN CHEMICALLY-MODIFIED BETA-CYCLODEXTRIN AND DEC-1-ENE - NEW PROSPECTS FOR BIPHASIC HYDROFORMYLATION OF WATER-INSOLUBLE OLEFINS
MONFLIER, E
FREMY, G
CASTANET, Y
MORTREUX, A
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (20): : 2269 - 2271
[9] Monflier E, 1997, NEW J CHEM, V21, P857

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